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Methyltrioxorhenium(VII) as an Oxidation Catalyst

โœ Scribed by Fritz E. Kuehn; Wolfgang A. Herrmann

Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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๐Ÿ“œ SIMILAR VOLUMES

Methyltrioxorhenium as Catalyst for Olef
Methyltrioxorhenium as Catalyst for Olefin Oxidation
โœ Prof. Dr. Wolfgang A. Herrmann; Richard W Fischer; Dr. Dieter W. Marz ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 473 KB ๐Ÿ‘ 1 views

The pronounced Lewis acidity explains the exceptional activity of the title compound as catalyst for olefin epoxidations with hydrogen peroxide. The system MTO/__t__BuOH/H~2~O~2~ transforms olefins selectively and efficiently into epoxides under very mild conditions (โˆ’30 to + 60ยฐC, but normally at r

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Methyltrioxorhenium(VII) in Oxidation Catalysis
โœ Fritz E. Kuehn ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons โš– 8 KB ๐Ÿ‘ 1 views

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Kinetics of oxidation and comproportiona
Kinetics of oxidation and comproportionation reactions involving an oxammonium ion, benzyl alcohol and methyltrioxorhenium(VII)
โœ Timothy H. Zauche; James H. Espenson ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 131 KB ๐Ÿ‘ 1 views

The reactions of 4-hydroxy-2,2,6,6-tetramethylpiperidinium N-oxide, an oxammonium ion abbreviated R 2 NO ฯฉ , have been studied. The previously unreported triflate salt was used in this study because the anions of the usual chloride and bromide salts can themselves be oxidized. Reactions between R 2