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Methyltrioxorhenium(VII) in Oxidation Catalysis

✍ Scribed by Fritz E. Kuehn

Publisher
John Wiley and Sons
Year
2006
Weight
8 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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PPh,)(CO),Cp,]+['21 or 3.008(2) 8, in [Mo,(p-StBu),-Further evidence of the high electrophilicity of 2 is the unusual hydride abstraction forced upon BH3 . THE This occurs quickly in dichloromethane at -30 "C and gives the novel unsaturated hydrido complex 4-PF6 in very high yield (CO),Cp]Z + 1131).