Methyl 4-{2-chloro-4-[2-(4,6-dimethoxypyrimidin-2-yloxy)benzylamino]phenoxy}benzoate
✍ Scribed by Chen, Zheng-Bo ;Wu, Jun ;Zhang, Pei-Zhi ;Wu, Dong-Dong
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 332 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, C 27 H 24 ClN 3 O 6 , a probable new herbicide, was synthesized by the reaction of 4,6-dimethoxy-2-(methylsulfonyl)pyrimidine and methyl 4-[2-chloro-4-(2-hydroxybenzylamino)phenoxy]benzoate in tetrahydrofuran. -Interactions occur between neighbouring benzene rings.
📜 SIMILAR VOLUMES
In the molecule of the title compound, C 15 H 13 ClN 2 O 4 , the pyrimidine and benzene rings form a dihedral angle of 69.3 (3) . Nostacking interactions are observed in the crystal structure.
The title phthalonitrile derivative, C 22 H 13 ClN 2 O 3 , contains three aromatic rings, which are not coplanar. The crystal structure is stabilized by intermolecular C-HÁ Á ÁN contacts.
In the title compound, C 14 H 15 ClN 2 O, the benzene and pyrimidine rings are nearly perpendicular, the dihedral angle between them being 84.7 (2) .