2-(2,4-Dichlorophenoxy)-N-(4,6-dimethoxypyrimidin-2-yl)propionamide
✍ Scribed by Liu, Guo-Hua ;Xue, Yun-Ning ;Yang, Lian-Zhun ;Yao, Mei ;Xue, Si-Jia
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 113 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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The title compound, C 27 H 24 ClN 3 O 6 , a probable new herbicide, was synthesized by the reaction of 4,6-dimethoxy-2-(methylsulfonyl)pyrimidine and methyl 4-[2-chloro-4-(2-hydroxybenzylamino)phenoxy]benzoate in tetrahydrofuran. -Interactions occur between neighbouring benzene rings.
In the title compound, C~10~H~13~Cl~2~O~4~PS, all bond lengths and angles are normal. The P atom is in a distorted tetrahedral configuration. In the crystal structure, intermolecular N—H...O hydrogen bonds link the molecules into chains running along the __b__ axis.
The title compound, C 19 H 18 N 4 O 8 , belonging to the pyrimidinyloxybenzoic acid family, exhibits herbicidal properties. The crystal structure is stabilized by C-HÁ Á ÁO and O-HÁ Á ÁN intermolecular hydrogen bonds.