The molecular conformation of the title compound, C~18~H~16~N~2~O, is stabilized by two intramolecular C—H...O interactions. The crystal packing is characterized by C—H...N hydrogen bonds.
4-(4-tert-Butylphenoxy)-2-chloropyrimidine
✍ Scribed by Liu, Wei-Min ;Zhu, You-Quan ;Wang, Yi-Feng ;Li, Gong-Chun ;Yang, Hua-Zheng
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 100 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C 14 H 15 ClN 2 O, the benzene and pyrimidine rings are nearly perpendicular, the dihedral angle between them being 84.7 (2) .
📜 SIMILAR VOLUMES
The title compound, C 18 H 16 N 2 O, contains a phthalonitrile ring lying on a crystallographic mirror plane and a 4-tert-butylphenoxy substituent oriented exactly perpendicular to that plane.
The title compound, C 27 H 24 ClN 3 O 6 , a probable new herbicide, was synthesized by the reaction of 4,6-dimethoxy-2-(methylsulfonyl)pyrimidine and methyl 4-[2-chloro-4-(2-hydroxybenzylamino)phenoxy]benzoate in tetrahydrofuran. -Interactions occur between neighbouring benzene rings.
The title phthalonitrile derivative, C 14 H 6 BrClN 2 O, contains two aromatic rings, which are almost perpendicular.
In the title compound, C 16 H 19 Cl 2 N 3 O 2 , the dihedral angle between the two rings is 86.26 (2) . The crystal packing is stabilized mainly by van der Waals interactions.