In the title molecule, C 15 H 12 ClNO 3 , the planar chlorophenyl moiety forms a dihedral angle of 60.70 (7) with the mean plane through the rest of the non-H atoms in the molecule. The carbonyl O atoms are involved in intramolecular NÐ HÁ Á ÁO and CÐHÁ Á ÁO hydrogen bonds. In the solid state, the m
Methyl 2-selenocyanatobenzoate
✍ Scribed by Jones, Peter G. ;Wismach, Cathleen ;Mugesh, Govindasamy ;du Mont, Wolf-Walther
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 216 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, C 9 H 7 NO 2 Se, displays an intramolecular SeÁ Á ÁO contact of 2.5614 (15) A Ê and an intermolecular SeÁ Á ÁN contact of 3.271 (2) A Ê . The molecule is approximately planar, the substituents being rotated by ca 5 out of the ring plane.
📜 SIMILAR VOLUMES
In the title molecule, C 16 H 17 NO 2 , there is an intramolecular hydrogen bond between the NH group and the O atom of the carbonyl group, but the crystal structure is devoid of intermolecular hydrogen bonding. The dihedral angle between the two benzene rings is 80.59 (5) .
In the title salt, C~10~H~10~N^+^·C~7~H~3~N~2~O~6~ ^−^, in addition to electrostatic interactions, the quinaldinium and 2,4-dinitrobenzoate ions are linked by N—H...O and C—H...O hydrogen bonds into a three-dimensional molecular network. The quinaldinium cations are stacked along the __a__ axis with