Methyl 2-(2,3-dimethylanilino)benzoate
✍ Scribed by Nawaz, Hamid ;Khawar Rauf, M. ;Ebihara, Masahiro ;Badshah, Amin
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 140 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title molecule, C 16 H 17 NO 2 , there is an intramolecular hydrogen bond between the NH group and the O atom of the carbonyl group, but the crystal structure is devoid of intermolecular hydrogen bonding. The dihedral angle between the two benzene rings is 80.59 (5) .
📜 SIMILAR VOLUMES
In the title compund, C~11~H~12~N~2~S, the whole molecule is essentially planar except for methyl H atoms, with a maximum deviation of 0.160 (2) Å for the aniline N atom. The molecule is stabilized by π–π interactions and intermolecular N—H...N hydrogen bonds, which produce dimers located about the
The crystal structure of the title compound, C 12 H 14 O 5 ÁH 2 O, displays a supramolecular structure via O-HÁ Á ÁO hydrogen bonds. Nostacking is observed.
The crystal structure of ethyl 2,3,5,6-tetramethylbenzoate, C 13 H 18 O 2 , has been determined and torsion angles are compared to those previously reported in a dipole moment study of substituted benzoates.
The title compound, C 9 H 7 NO 2 Se, displays an intramolecular SeÁ Á ÁO contact of 2.5614 (15) A Ê and an intermolecular SeÁ Á ÁN contact of 3.271 (2) A Ê . The molecule is approximately planar, the substituents being rotated by ca 5 out of the ring plane.