2-Methylquinolinium 2,4-dinitrobenzoate
✍ Scribed by Rosli, Mohd Mustaqim ;Fun, Hoong-Kun ;Razak, Ibrahim Abdul ;Rodwatcharapiban, Pinanong ;Chantrapromma, Suchada
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 269 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title salt, C~10~H~10~N^+^·C~7~H~3~N~2~O~6~
^−^, in addition to electrostatic interactions, the quinaldinium and 2,4-dinitrobenzoate ions are linked by N—H...O and C—H...O hydrogen bonds into a three-dimensional molecular network. The quinaldinium cations are stacked along the a axis with a centroid–centroid distance of 3.4662 (7) Å, indicating π–π interactions.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.056 wR factor = 0.119 Data-to-parameter ratio = 14.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C 9 H 7 NO 2 Se, displays an intramolecular SeÁ Á ÁO contact of 2.5614 (15) A Ê and an intermolecular SeÁ Á ÁN contact of 3.271 (2) A Ê . The molecule is approximately planar, the substituents being rotated by ca 5 out of the ring plane.
In the title molecule, C 15 H 12 ClNO 3 , the planar chlorophenyl moiety forms a dihedral angle of 60.70 (7) with the mean plane through the rest of the non-H atoms in the molecule. The carbonyl O atoms are involved in intramolecular NÐ HÁ Á ÁO and CÐHÁ Á ÁO hydrogen bonds. In the solid state, the m