The title phthalonitrile derivative, C 22 H 13 ClN 2 O 3 , contains three aromatic rings, which are not coplanar. The crystal structure is stabilized by intermolecular C-HÁ Á ÁN contacts.
Methyl 2-(2-chlorobenzamido)benzoate
✍ Scribed by Yadav, Bishwa Nath ;Prasad, Shambhu ;Prasad, Satya Murti
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 180 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the title molecule, C 15 H 12 ClNO 3 , the planar chlorophenyl moiety forms a dihedral angle of 60.70 (7) with the mean plane through the rest of the non-H atoms in the molecule. The carbonyl O atoms are involved in intramolecular NÐ HÁ Á ÁO and CÐHÁ Á ÁO hydrogen bonds. In the solid state, the molecules exist as centrosymmetric CÐHÁ Á ÁO hydrogenbonded dimers.
📜 SIMILAR VOLUMES
The crystal structure of the title compound, C 12 H 14 O 5 ÁH 2 O, displays a supramolecular structure via O-HÁ Á ÁO hydrogen bonds. Nostacking is observed.
The molecule of the title compound, C 18 H 8 Cl 3 F 3 N 4 O, is a tricyclic amide with an overall U-shape. Intermolecular N-HÁ Á ÁN hydrogen bonds, with an N(amide)Á Á ÁN(cyano) separation of 3.051 (4) A ˚, link the molecules into linear chains along the c axis.
In the title molecule, C 16 H 17 NO 2 , there is an intramolecular hydrogen bond between the NH group and the O atom of the carbonyl group, but the crystal structure is devoid of intermolecular hydrogen bonding. The dihedral angle between the two benzene rings is 80.59 (5) .