𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Mechanistic Studies on Thiaminase I: 1. The Stereochemical Course of the Reaction

✍ Scribed by R. Nicewonger; A. Rammelsberg; C.A. Costello; T.P. Begley

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
262 KB
Volume
23
Category
Article
ISSN
0045-2068

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Mechanistic Studies on Thiaminase I: Ide
Mechanistic Studies on Thiaminase I: Identification of the Product of Thiamin Degradation in the Absence of the Nucleophilic Cosubstrate
✍ Min Wu; Elizabeth T. Papish; Tadhg P. Begley πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 English βš– 46 KB

Thiaminase I catalyzes the decomposition of thiamin under basic conditions in the absence of the nucleophilic cosubstrate. The product of this reaction was identified as the adduct resulting from the displacement of the thiazole moiety of thiamin by the ring opened form of thiamin.

A Study of the Stereochemical Course of
A Study of the Stereochemical Course of Ξ²-Oxygen Elimination with a Rhodium(I) Complex
✍ Masahiro Murakami; Hideyuki Igawa πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 German βš– 79 KB

## Abstract The stereochemical course of __Ξ²__‐oxygen elimination of an organorhodium(I) complex was investigated through the Rh‐catalyzed addition of phenylboronic acid to a chiral propargyl acetate to produce an allene. The degree of chirality transfer suggests that the __Ξ²__‐oxygen elimination t