Mechanistic studies on the rhodium complex catalyzed hydroformylation reaction of olefins
✍ Scribed by A.M. Trzeciak; J.J. Ziółkowski
- Publisher
- Elsevier Science
- Year
- 1983
- Weight
- 943 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0304-5102
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## Mechanistic Aspects of Asymmetric Hydroformylation of Olefins Catalyzed by Chiral Phosphine-Phosphite-Rhodium(I) Complexes. -The effects of the partial pressure of CO (II) and H2 on the reaction rate and selectivity of the asymmetric hydroformylation of 1-hexene ( Ia) and styrene (Ib) are exam
SiO 2 -tethered rhodium complexes deriving from Rh(CO) 2 acac and the commercially available 3-(mercapto)propyl-and 3-(1thioureido)propyl-functionalyzed silica gel, respectively, have been used as catalysts in the hydroformylation of some functionalized olefins directed to the preparation of interme