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A Study of the Stereochemical Course of β-Oxygen Elimination with a Rhodium(I) Complex

✍ Scribed by Masahiro Murakami; Hideyuki Igawa

Publisher
John Wiley and Sons
Year
2002
Tongue
German
Weight
79 KB
Volume
85
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The stereochemical course of β‐oxygen elimination of an organorhodium(I) complex was investigated through the Rh‐catalyzed addition of phenylboronic acid to a chiral propargyl acetate to produce an allene. The degree of chirality transfer suggests that the β‐oxygen elimination takes place in both syn and anti modes.

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