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Mechanistic aspects of metal-catalyzed alternating copolymerization of olefins with carbon monoxide

✍ Scribed by Sen, Ayusman

Book ID
121468314
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
792 KB
Volume
26
Category
Article
ISSN
0001-4842

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## Abstract The cobalt‐catalyzed alternating copolymerization of epoxides and CO is a novel, direct approach to aliphatic polyesters, such as poly(hydroxybutyrate) (PHB). This reaction was found to be catalyzed by Ph~3~Si[Co(CO)~4~] (4) and pyridine affording in a first step the stable mono‐inserti