Enantioselective, alternating copolymerization of carbon monoxide and olefins
β Scribed by Jian-Chao Yuan; Shi-Jie Lu
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 127 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0887-624X
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The cobaltβcatalyzed alternating copolymerization of epoxides and CO is a novel, direct approach to aliphatic polyesters, such as poly(hydroxybutyrate) (PHB). This reaction was found to be catalyzed by Ph~3~Si[Co(CO)~4~] (4) and pyridine affording in a first step the stable monoβinserti
The alternating copolymer of ethylene and carbon monoxide (POK) has properties that suggest possible utility for fibers. However, in order to be melt spinnable, the copolymer should be stable somewhat above its melt temperature for some minutes. Research to improve the stability of POK was carried o