Enantioselective alternating copolymerization of carbon monoxide with propylene, 1-heptene, 1-octene, and styrene was carried out using a palladium catalyst modified by 1,4-3,6-dianhydro-2,5-dideoxy-2,5-bis(diphenylphosphino)-L-iditol (DDPPI). The pure poly(1,4-ketone)s were obtained by dissolving t
✦ LIBER ✦
Alternating copolymerization of carbon monoxide and α-olefins
✍ Scribed by James C. W. Chien; Allen X. Zhao; Frank Xu
- Publisher
- Springer
- Year
- 1992
- Tongue
- English
- Weight
- 164 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0170-0839
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Typical Copolymerisation. A mixture of [Pd(OAc),] (0.06 mmol), dicyclohexyl{(R)-1 -[(S)-2-(diphenylphosphino)ferrocenyl]ethyl}phosphine (Za; 0.07 mmol), Ni(CIO,), . 6H20 (0.3 mmol), and naphtho-l,rl-quinone (3.0 rnmol) in 151.5 ml of THF, 8.5 rnl of MeOH, and 2.0 ml of CH(OMe), was introduced under