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Mechanistic aspects of the alternating copolymerization of carbon monoxide with olefins catalyzed by cationic palladium complexes

✍ Scribed by Batistini, Antonio; Consiglio, Giambattista


Book ID
127367037
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
441 KB
Volume
11
Category
Article
ISSN
0276-7333

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## Abstract The cobalt‐catalyzed alternating copolymerization of epoxides and CO is a novel, direct approach to aliphatic polyesters, such as poly(hydroxybutyrate) (PHB). This reaction was found to be catalyzed by Ph~3~Si[Co(CO)~4~] (4) and pyridine affording in a first step the stable mono‐inserti