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Enantioselective Alternating Copolymerization of α-Olefins with Carbon Monoxide Using a Cationic Palladium−Chiral Diphosphine Complex

✍ Scribed by Yuan, Jian-Chao; Lu, Shi-Jie


Book ID
127126670
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
97 KB
Volume
20
Category
Article
ISSN
0276-7333

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✍ Jian-Chao Yuan; Shi-Jie Lu 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 116 KB

Enantioselective alternating copolymerization of carbon monoxide with propylene, 1-heptene, 1-octene, and styrene was carried out using a palladium catalyst modified by 1,4-3,6-dianhydro-2,5-dideoxy-2,5-bis(diphenylphosphino)-L-iditol (DDPPI). The pure poly(1,4-ketone)s were obtained by dissolving t