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Mechanisms of oxidation of phenol and cyclohexene by an oxo complex of ruthenium(IV)

โœ Scribed by Seok, Won K.; Dobson, John C.; Meyer, Thomas J.

Book ID
120618695
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
340 KB
Volume
27
Category
Article
ISSN
0020-1669

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๐Ÿ“œ SIMILAR VOLUMES

Kinetics and catalysis of oxidation of p
Kinetics and catalysis of oxidation of phenol by ruthenium(IV)โ€“oxo complex
โœ Debabrata Chatterjee; Anannya Mitra ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 436 KB

Kinetics of oxidation of phenol by [Ru IV (tpy)(pic)(O)] + (tpy = 2,2 ,6 ,2 -terpyridine; pic -= picolinate) (1) has been studied in aqueous solution using a rapid scan stopped-flow spectrophotometer. Under pseudo-first order conditions of excess phenol concentrations, the rate of reaction was found