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Oxidation of thioanisoles and methyl phenyl sulfoxides by oxo(phosphine)ruthenium(IV) complexes

✍ Scribed by Acquaye, John Henry; Muller, James G.; Takeuchi, Kenneth J.

Book ID
127056084
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
729 KB
Volume
32
Category
Article
ISSN
0020-1669

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πŸ“œ SIMILAR VOLUMES

Kinetics and catalysis of oxidation of p
Kinetics and catalysis of oxidation of phenol by ruthenium(IV)–oxo complex
✍ Debabrata Chatterjee; Anannya Mitra πŸ“‚ Article πŸ“… 2008 πŸ› Elsevier Science 🌐 English βš– 436 KB

Kinetics of oxidation of phenol by [Ru IV (tpy)(pic)(O)] + (tpy = 2,2 ,6 ,2 -terpyridine; pic -= picolinate) (1) has been studied in aqueous solution using a rapid scan stopped-flow spectrophotometer. Under pseudo-first order conditions of excess phenol concentrations, the rate of reaction was found