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Oxidation of Aryl Methyl Sulfoxides by Oxo(salen)manganese(V) Complexes and the Reactivity−Selectivity Principle †

✍ Scribed by Chellamani, Arunachalam; Kulanthaipandi, Periasamy; Rajagopal, Seenivasan

Book ID
125466276
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
103 KB
Volume
64
Category
Article
ISSN
0022-3263

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Mechanistic study on the oxidation of (phenylthio)acetic acids by oxo(salen)manganese(V) complexes and the reactivity–selectivity principle
✍ Arunachalam Chellamani; Paramasivan Sengu 📂 Article 📅 2008 🏛 Elsevier Science 🌐 English ⚖ 427 KB

A systematic study on the kinetics and mechanism of oxidation of several (para-substituted phenylthio)acetic acids with various substituted oxo(salen)manganese(V) complexes in acetonitrile at 20 • C is presented. The kinetic data indicate that the reaction is second-order overall, firstorder each in