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Applicability and mathematical verification of the reactivity–selectivity principle in the oxidation of thioanisoles by oxo(salen)manganese(V) complexes

✍ Scribed by Chellamani, Arunachalam; Alhaji, Naina Mohammed Ismail; Rajagopal, Seenivasan


Book ID
115464526
Publisher
Royal Society of Chemistry
Year
1997
Tongue
English
Weight
335 KB
Volume
2
Category
Article
ISSN
1472-779X

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A systematic study on the kinetics and mechanism of oxidation of several (para-substituted phenylthio)acetic acids with various substituted oxo(salen)manganese(V) complexes in acetonitrile at 20 • C is presented. The kinetic data indicate that the reaction is second-order overall, firstorder each in