The electrocatalytic oxidation of methanol by a ruthenium(V) oxo complex
β Scribed by Yip-Kai Lai; Kwok-Yin Wong
- Book ID
- 107750210
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 616 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0013-4686
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π SIMILAR VOLUMES
Kinetics of oxidation of phenol by [Ru IV (tpy)(pic)(O)] + (tpy = 2,2 ,6 ,2 -terpyridine; pic -= picolinate) (1) has been studied in aqueous solution using a rapid scan stopped-flow spectrophotometer. Under pseudo-first order conditions of excess phenol concentrations, the rate of reaction was found
## Abstract The intrinsic reactivity of a manganese(V)βoxo porphyrin complex, a typically fleeting intermediate in catalytic oxidation reactions in solution, has been elucidated in a study focused on its gasβphase ionβchemistry. The naked highβvalent Mn^V^βoxo porphyrin intermediate **1** ([(tpfpp)