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Surface Control of Oxidation by an Adsorbed Ru IV −Oxo Complex

✍ Scribed by Gallagher, Laurie A.; Meyer, Thomas J.

Book ID
126226044
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
79 KB
Volume
123
Category
Article
ISSN
0002-7863

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✍ Debabrata Chatterjee; Anannya Mitra 📂 Article 📅 2008 🏛 Elsevier Science 🌐 English ⚖ 436 KB

Kinetics of oxidation of phenol by [Ru IV (tpy)(pic)(O)] + (tpy = 2,2 ,6 ,2 -terpyridine; pic -= picolinate) (1) has been studied in aqueous solution using a rapid scan stopped-flow spectrophotometer. Under pseudo-first order conditions of excess phenol concentrations, the rate of reaction was found