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Electrochemical Oxidation of Water by an Adsorbed μ-Oxo-Bridged Ru Complex

✍ Scribed by Liu, Feng; Cardolaccia, Thomas; Hornstein, Brooks J.; Schoonover, Jon R.; Meyer, Thomas J.

Book ID
120595241
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
58 KB
Volume
129
Category
Article
ISSN
0002-7863

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Water oxidation catalyzed by dimeric μ-o
Water oxidation catalyzed by dimeric μ-oxo bridged ruthenium diimine complexes
✍ James K. Hurst 📂 Article 📅 2005 🏛 Elsevier Science 🌐 English ⚖ 520 KB

Dimeric -oxo ions such as cis,cis-[(bpy) 2 Ru(OH 2 )] 2 O 4+ , its congeners containing ring-substituted bipryidine ligands, and related structures have long been known to efficiently catalyze water oxidation by strong chemical oxidants and at electrode surfaces. However, despite considerable effort