Under inert atmosphere, dimethyldioxirane 1 converts benzaldehydes solely to the corresponding acids; the reaction is insensitive to electronic effects; yields are limited by the competing decomposition of 1 to acetol; Q2 trapping of free-radical intermediates is observed. Dioxiranes, three-membered
โฆ LIBER โฆ
Mechanisms of Oxidation of Benzaldehyde
โ Scribed by MULCAHY, M. F. R.; WATT, I. C.
- Book ID
- 109567812
- Publisher
- Nature Publishing Group
- Year
- 1951
- Tongue
- English
- Weight
- 206 KB
- Volume
- 168
- Category
- Article
- ISSN
- 0028-0836
- DOI
- 10.1038/168123a0
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