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Kinetics and mechanism of the oxidation of substituted benzaldehydes by hexamethylenetetramine-bromine

✍ Scribed by H. Gangwani; P. K. Sharma; K. K. Banerji


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
103 KB
Volume
32
Category
Article
ISSN
0538-8066

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The oxidation of lower oxyacids of phosphorus by hexamethylenetetramine bromine (HABR) in glacial acetic acid resulted in the formation of corresponding oxyacids with phosphorus in a higher oxidation state. The reaction exhibited stoichiometry. The reaction 2 : 1 is first order with respect to HABR.

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The kinetics and mechanism of the reaction between nitrous acid and bromine are studied in dilute sulfuric acid medium, using both the stopped-flow method and conventional spectrophotometry. The partial reaction order with respect to Br 2 moderately differs from 1, showing a saturation at a higher c

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The kinetics of oxidation of four vicinal diols, four nonvicinal diols, and one of their monoethers by pyridinium bromochromate (PBC) have been studied in dimethyl sulfoxide. The main product of oxidation is the corresponding hydroxyaldehyde. The reaction is first-order with respect to each the diol