Kinetics and correlation analysis of reactivity in oxidation of organic sulfides by hexamethylenetetramine–bromine
✍ Scribed by Kirti Choudhary; Deepa Suri; Seema Kothari; Kalyan K. Banerji
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 89 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0894-3230
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The oxidation of lower oxyacids of phosphorus by hexamethylenetetramine bromine (HABR) in glacial acetic acid resulted in the formation of corresponding oxyacids with phosphorus in a higher oxidation state. The reaction exhibited stoichiometry. The reaction 2 : 1 is first order with respect to HABR.
The kinetics and mechanism of the reaction between nitrous acid and bromine are studied in dilute sulfuric acid medium, using both the stopped-flow method and conventional spectrophotometry. The partial reaction order with respect to Br 2 moderately differs from 1, showing a saturation at a higher c
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BBCP was prepared by the reported method . The preparation, purification, and specification of the substituted benzyl alcohols and ␣,␣-dideuteriobenzyl alcohol (PhCD 2 OH) have been described earlier . Acetic acid was refluxed with chromic oxide and acetic anhydride for 6 h and then fractionated. Pe