Dimethyldioxirane: Mechanism of benzalde
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A.L. Baumstark; M. Beeson; P.C. Vasquez
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Article
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1989
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Elsevier Science
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French
โ 317 KB
Under inert atmosphere, dimethyldioxirane 1 converts benzaldehydes solely to the corresponding acids; the reaction is insensitive to electronic effects; yields are limited by the competing decomposition of 1 to acetol; Q2 trapping of free-radical intermediates is observed. Dioxiranes, three-membered