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Mechanism of the oxidation of alkyl aryl sulfides by phenyliodoso diacetate

โœ Scribed by Srinivasan, Chockalingam; Chellamani, Arunachalam; Kuthalingam, Packiam

Book ID
124161863
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
532 KB
Volume
47
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

Effective asymmetric oxidation of enones
Effective asymmetric oxidation of enones and alkyl aryl sulfides
โœ Melissa Hinch; Olivier Jacques; Carmelo Drago; Lorenzo Caggiano; Richard F.W. Ja ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 385 KB

Asymmetric epoxidation of aliphatic enones can be achieved with good conversions and high levels of enantiomeric excess using a catalyst, formulated as 6, derived from dibutylmagnesium and a range of dialkyl tartrates, with tert-butylhydroperoxide as the oxidant. This process works best with the add