Mechanism of the oxidation of alkyl aryl and diphenyl sulfides by chromium(VI)
โ Scribed by Srinivasan, Chockalingam; Chellamani, Arunachalam; Rajagopal, Seenivasan
- Book ID
- 126918291
- Publisher
- American Chemical Society
- Year
- 1985
- Tongue
- English
- Weight
- 660 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
## Abstract Reactions of diphenyl sulfide with the two oxidants peroxydisulfate and peroxydiphosphate are described. With each oxidant, the reaction is first order in the oxidant and zero order in the substrate. The rate of the reaction is also independent of the effect of the substituent. Hydrogen
Asymmetric epoxidation of aliphatic enones can be achieved with good conversions and high levels of enantiomeric excess using a catalyst, formulated as 6, derived from dibutylmagnesium and a range of dialkyl tartrates, with tert-butylhydroperoxide as the oxidant. This process works best with the add