Asymmetric epoxidation of aliphatic enones can be achieved with good conversions and high levels of enantiomeric excess using a catalyst, formulated as 6, derived from dibutylmagnesium and a range of dialkyl tartrates, with tert-butylhydroperoxide as the oxidant. This process works best with the add
โฆ LIBER โฆ
Substituent and steric effects in the oxidation of alkyl aryl sulfides by peroxydisulfate
โ Scribed by Srinivasan, C.; Kuthalingam, P.; Arumugam, N.
- Book ID
- 124093943
- Publisher
- NRC Research Press
- Year
- 1978
- Tongue
- French
- Weight
- 197 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0008-4042
- DOI
- 10.1139/v78-497
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## Abstract The pyrolyses of __p__โnitrophenyl __t__โbutyl ether, __p__โmethoxyphenyl __t__โbutyl ether, __p__โaminophenyl __t__โbutyl ether, __p__โnitrophenyl __t__โbutyl sulfide, and propargyl __t__โbutyl sulfide have been studied in a stirredโflow reactor over the temperature range 430โ530ยฐC and