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Oxidation of alkyl sulfides by aqueous peroxymonosulfate

โœ Scribed by Betterton, Eric A.


Book ID
121251990
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
831 KB
Volume
26
Category
Article
ISSN
0013-936X

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Diastereoselective oxidation of sulfides
โœ George J. Quallich; J. William Lackey ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 153 KB

Potassium peroxymonosulfate oxidation of suffides to suffoxides occurs with high diastereosebctivky. In seeking a preparative process for the skfe chain of antibacterial CP-70,429, penem 1. we prepared the sulfoxkle side chain a as a 4:l mixture of ~6~6 and & sulfoxides by oxkfatbn of the sulfide 2