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Sulfide oxidation and oxidative hydrolysis of thioesters by peroxymonosulfate ion

✍ Scribed by Bunton, Clifford A.; Foroudian, Houshang J.; Kumar, Anurag

Book ID
118201928
Publisher
Royal Society of Chemistry
Year
1995
Tongue
English
Weight
901 KB
Volume
1
Category
Article
ISSN
1472-779X

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πŸ“œ SIMILAR VOLUMES

OXIDATIVE HYDROLYSIS OF PHOSPHORUS(V) ES
OXIDATIVE HYDROLYSIS OF PHOSPHORUS(V) ESTERS OF THIOLS BY PEROXYMONOSULFATE ION. REACTIONS OF PEROXYMONOSULFATE ION WITH PHOSPHORUS(V) ESTERS OF THIOLS
✍ Andrei BlaskΓ³; Clifford A. Bunton; Anurag Kumar πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 172 KB πŸ‘ 2 views

Peroxymonosulfate ion, HSO Οͺ 5 , as Oxone, readily converts phosphorus(V) esters of thiols into the phosphorus(V) and sulfonic acids. The esters were Ph 2 PO β€’ SC 6 H 4 R(p) with R = MeO (1a), Me (1b), H (1c), Cl (1d) and NO 2 (1e), (EtO) 2 PO β€’ SPh (2), Ph 2 OI β€’ SEt (3) and PhPO(OEt)SEt (4). React