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Mechanism of catalysis in aminolysis of esters in an aprotic medium

✍ Scribed by Yu. I. Khurgin; M. G. Dmitrieva

Book ID
112438039
Publisher
Springer
Year
1974
Tongue
English
Weight
203 KB
Volume
23
Category
Article
ISSN
1573-9171

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Kinetics and mechanism of aminolysis of
Kinetics and mechanism of aminolysis of aliphatic esters in aprotic solvents
✍ Agu-TΓ΅nis Talvik; Ants Tuulmets; Evi Vaino πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 52 KB πŸ‘ 2 views

Kinetic studies were carried out on the aminolysis reactions of substituted aliphatic esters in a variety of aprotic solvents. The reaction rate is strongly affected by inductive and steric effects of substituents in the acyl group, rising more than 10 4 -fold from cyanoacetate to trifluoroacetate.