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Mechanism of Ester Aminolysis in Aprotic Media and Specific Solvent Effects

✍ Scribed by Otto B. Nagy; Victor Reuliaux; Nicole Bertrand; Anne van Der Mensbrugghe; Jean Leseul; Janos B. Nagy

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
774 KB
Volume
94
Category
Article
ISSN
0037-9646

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πŸ“œ SIMILAR VOLUMES

Kinetics and mechanism of aminolysis of
Kinetics and mechanism of aminolysis of aliphatic esters in aprotic solvents
✍ Agu-TΓ΅nis Talvik; Ants Tuulmets; Evi Vaino πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 52 KB πŸ‘ 2 views

Kinetic studies were carried out on the aminolysis reactions of substituted aliphatic esters in a variety of aprotic solvents. The reaction rate is strongly affected by inductive and steric effects of substituents in the acyl group, rising more than 10 4 -fold from cyanoacetate to trifluoroacetate.