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The aminolysis of carbamates. II. The Kinetics and Mechanism of the Aminolysis of Benzyl N-phenylcarbamate with ethanolamine in aprotic solvents

✍ Scribed by Vasile Löcsei; Otilia Facsko; Traian Chirilâ


Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
290 KB
Volume
325
Category
Article
ISSN
1615-4150

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The aminolysis of carbamates. I. The Kin
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Kinetic studies of the reactions of p-nitrophenyl N-phenylcarbamates with benzylamines were carried out in acetonitrile at 25•0 °C. Second-order (k 2 ) and third-order (k 3 ) rate constants were observed for all the Y-substituted carbamates except for Y = m Ϫ Cl. The relatively large magnitude of X