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Aminolysis of phenyl salicylate in acetonitrile. A study of intramolecular catalysis in an aprotic solvent

✍ Scribed by Menger, Fred M.; Smith, Jerry H.

Book ID
120556186
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
476 KB
Volume
91
Category
Article
ISSN
0002-7863

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Pseudo-first-order rate constants (k 1 ) for the reaction of ethane-1,2-diol (DOL) with ionized phenyl salicylate (PS Γ€ ), obtained in mixed DOL-CH 3 CN solvent at constant [H 2 O] and [NaOH], obey the relationship , where a is the apparent second-order rate constant, K A is the association constan