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Crown ether salt catalysis of ester aminolysis in an aprotic solvent

✍ Scribed by Kőmives, T. ;Márton, A. F. ;Dutka, F. ;Lőw, M. ;Kisfaludy, L.

Book ID
112684301
Publisher
Springer
Year
1980
Tongue
English
Weight
118 KB
Volume
13
Category
Article
ISSN
0133-1736

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Kinetics and mechanism of aminolysis of
Kinetics and mechanism of aminolysis of aliphatic esters in aprotic solvents
✍ Agu-Tõnis Talvik; Ants Tuulmets; Evi Vaino 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 52 KB 👁 2 views

Kinetic studies were carried out on the aminolysis reactions of substituted aliphatic esters in a variety of aprotic solvents. The reaction rate is strongly affected by inductive and steric effects of substituents in the acyl group, rising more than 10 4 -fold from cyanoacetate to trifluoroacetate.