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Mechanism of Asymmetric Hydrogenation of α-(Acylamino)acrylic Esters Catalyzed by BINAP−Ruthenium(II) Diacetate

✍ Scribed by Kitamura, Masato; Tsukamoto, Masaki; Bessho, Yuhki; Yoshimura, Masahiro; Kobs, Uwe; Widhalm, Michael; Noyori, Ryoji


Book ID
125457717
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
360 KB
Volume
124
Category
Article
ISSN
0002-7863

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The asymmetric hydrogenation of N-tosylimines was accomplished with a catalytic amount of Ru[(R)-2,2'-bis(diphenylphosphlno)-l,l'-binaphthyl](O2CCH3)2 to afford the corresponding amines in high enantiomeric excesses.