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Mechanism of Asymmetric Hydrogenation of Ketones Catalyzed by BINAP/1,2-Diamine−Ruthenium(II) Complexes

✍ Scribed by Sandoval, Christian A.; Ohkuma, Takeshi; Muñiz, Kilian; Noyori, Ryoji

Book ID
120938485
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
281 KB
Volume
125
Category
Article
ISSN
0002-7863

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Asymmetric hydrogenation of N-tosylimine
Asymmetric hydrogenation of N-tosylimines catalyzed by BINAP-ruthenium(II) complexes
✍ AndréB. Charette; André Giroux 📂 Article 📅 1996 🏛 Elsevier Science 🌐 French ⚖ 208 KB

The asymmetric hydrogenation of N-tosylimines was accomplished with a catalytic amount of Ru[(R)-2,2'-bis(diphenylphosphlno)-l,l'-binaphthyl](O2CCH3)2 to afford the corresponding amines in high enantiomeric excesses.