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ChemInform Abstract: Asymmetric Hydrogenation of N-Tosylimines Catalyzed by BINAP-Ruthenium( II) Complexes.

✍ Scribed by A. B. CHARETTE; A. GIROUX

Book ID
112041939
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
27
Category
Article
ISSN
0931-7597

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Asymmetric hydrogenation of N-tosylimine
Asymmetric hydrogenation of N-tosylimines catalyzed by BINAP-ruthenium(II) complexes
✍ AndrΓ©B. Charette; AndrΓ© Giroux πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 French βš– 208 KB

The asymmetric hydrogenation of N-tosylimines was accomplished with a catalytic amount of Ru[(R)-2,2'-bis(diphenylphosphlno)-l,l'-binaphthyl](O2CCH3)2 to afford the corresponding amines in high enantiomeric excesses.