The rate constant for the reaction NHa + OH + NH= + Hz0 was determined by the comparison of the calculated induo tion period data with experiments by the shock tube technique in the range 1360-1840 K, for NHs-Ha-02-\_Ar mixtures\_ The rate constants can be represented by the expression k = 1012-4g'o
MCSCF reaction-path energetics and thermal rate-constants for the reaction of3NH with H2
✍ Scribed by Josef Ischtwan; Peter Schwerdtfeger; Sigrid D. Peyerimhoff; Michael A. Collins; Trygve Helgaker; Poul Jørgensen; Hans Jørgen Aa. Jensen
- Book ID
- 105085218
- Publisher
- Springer
- Year
- 1994
- Tongue
- English
- Weight
- 729 KB
- Volume
- 89
- Category
- Article
- ISSN
- 1432-2234
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The rate constant of the reaction, OH + NH3 -+ Hz0 + NH2, has been measured at temperatures between 230 and 490'K using time-resolved resonance absorption to observe the concemytion of OH radicals..An Arrhenius expression, kI = 2.3 X lO\_" exp(-1.6 kcai mole-'/RT) cm3 molecule-' set , was obtained.
Ck~sical trajectory cakuk~tions for the collinea\_r H+H2 exchange reaction weie performed QSiIIg the same poten-. ## I&J merg surface pretiou+ly adopted for exact quantum mechanical calculationr Reactions of bath sound state amjv-ibrationdy excited aate reagent were wwidered, over a relative kine
The rate c&Want and the product distriblition for the reaction of D; w&h I& has been masured as a function of the Dz vibrational energy. in these experiments a mass analyzed bfzam of D3 ions is de&crated to le& than 0.1 eV and is subsequently injected into an ion cyclotron resonance (ICR) cell where