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Matrix-Isolation Study of the Reaction of Atomic and Molecular Fluorine with Carbon Atoms. The Infrared Spectra of Normal and 13C-Substituted CF2 and CF3

โœ Scribed by Milligan, Dolphus E.


Book ID
120932413
Publisher
American Institute of Physics
Year
1968
Tongue
English
Weight
785 KB
Volume
48
Category
Article
ISSN
0021-9606

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Using a relative rate technique the reactions of chlorine and fluorine atoms with CF3CHO have been determined to proceed with rate constants of (1.8 % 0.4) x and (2.7 2 0.1) x lo-" cm3 molecule-' s-', respectively. Experiments were performed a t 295 ? 2 K and 700 torr total pressure of nitrogen. The