## Abstract __Cine__ nucleophilic substitution of 1,4‐dinitroimidazole and its 2‐methyl derivative with nitrogen‐15 or carbon‐13 potassium cyanides afforded, respectively, labelled 4(5)‐nitro‐1H‐imidazole‐5(4)‐carbonitriles. Detailed mass spectra analysis led to the conclusion that during fragmenta
Mass spectrometry of imidazole-4(5)-carboxaldehyde and some 1-methyl and nitro derivatives
✍ Scribed by Arturo Cert; Pedro Delgado-Cobos; Mariana Trujillo Pérez-Lanzac
- Publisher
- John Wiley and Sons
- Year
- 1986
- Tongue
- English
- Weight
- 571 KB
- Volume
- 21
- Category
- Article
- ISSN
- 1076-5174
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📜 SIMILAR VOLUMES
A simple four-stage conversion of 2-1nethyl-4(5>nitroimidazole to 2-methyl-4(5)-nitr0['~N""]imidazole is reported. The method consists in N-nitration of the initial compound to ?-methyl-1,4-dinitroimidazole, treating the latter with ["Nlglycine and N-dealkylation of the obtained (~-rnethyl-4-nitro[~
## Abstract magnified image Oxidation of metronidazole (**4**) with sodium dichromate yielded the corresponding 2‐(2‐methyl‐5‐nitro‐1__H__‐imidazol‐1‐yl)acetic acid (**5**) which was esterified with 1‐butanol to give butyl 2‐(2‐methyl‐5‐nitro‐1__H__‐imidazol‐1‐yl)acetate (**8**). Reaction of the l