Magnetic Susceptibility and Peculiarity of Chemical Bond in the Cd-P(As) System Compounds
β Scribed by Ts. Z. Vitkina; A. U. Sheleg
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 151 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0232-1300
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π SIMILAR VOLUMES
An ampule reaction between Mo and PCl 5 at 200 Β°C yielded (PCl 4 ) 2 [Mo 2 Cl 10 ], the first ternary compound in MoΒ±PΒ±Cl system. Single crystal X-ray diffraction gave a triclinic unit cell: a = 6.870(1), b = 8.892(2), c = 9.423(2) A Γ , Ξ± = 100.24(2), b = 95.55(2), c = 96.12(2)Β°(V = 559.3(2) A Γ 3
The bonding in the As 6 4Γ ion is studied in the unusually low-coordination environment provided by the compound {Rb[18]crown-6)} 2 Rb 2 As 6 β’6 NH 3 . Theoretical analysis of the related P 6 4Γ ion indicates an unusual PΒΌP bond which contains major contributions from the lone pairs. Outside a highl