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ChemInform Abstract: Synthesis, Crystal Structure, and Bonding of (PCl4)2[Mo2Cl10], the First Compound in the Mo—P—Cl System.

✍ Scribed by G. V. KHVORYKH; S. I. TROYANOV; A. I. BARANOV; A. A. SEROV


Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
29
Category
Article
ISSN
0931-7597

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Synthesis, Crystal Structure, and Bondin
✍ G. V. Khvorykh; S. I. Troyanov; A. I. Baranov; A. A. Serov 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 88 KB 👁 1 views

An ampule reaction between Mo and PCl 5 at 200 °C yielded (PCl 4 ) 2 [Mo 2 Cl 10 ], the first ternary compound in Mo±P±Cl system. Single crystal X-ray diffraction gave a triclinic unit cell: a = 6.870(1), b = 8.892(2), c = 9.423(2) A Ê , α = 100.24(2), b = 95.55(2), c = 96.12(2)°(V = 559.3(2) A Ê 3