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ChemInform Abstract: Tetrachlorophosphonium Chlorometallates of Rhenium and Molybdenum: Syntheses, Crystal Structures, and Magnetism of [PCl4]2[Re2Cl10] and [PCl4]3[ReCl6]2, and the Magnetic Properties of [PCl4]2[Mo2Cl10].

✍ Scribed by J. Beck; K. Mueller-Buschbaum; F. Wolf

Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
30
Category
Article
ISSN
0931-7597

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Synthesis, Crystal Structure, and Bonding of (PCl4)2[Mo2Cl10], the First Compound in Mo–P–Cl System
✍ G. V. Khvorykh; S. I. Troyanov; A. I. Baranov; A. A. Serov πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 German βš– 88 KB πŸ‘ 1 views

An ampule reaction between Mo and PCl 5 at 200 °C yielded (PCl 4 ) 2 [Mo 2 Cl 10 ], the first ternary compound in Mo±P±Cl system. Single crystal X-ray diffraction gave a triclinic unit cell: a = 6.870(1), b = 8.892(2), c = 9.423(2) A Ê , α = 100.24(2), b = 95.55(2), c = 96.12(2)°(V = 559.3(2) A Ê 3