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ChemInform Abstract: Synthesis and Crystal Structure of (PCl4)[Re2Cl9].

✍ Scribed by A. I. Baranov; G. V. Khvorykh; S. I. Troyanov

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
30
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Synthesis and Crystal Structure of (PCl4
Synthesis and Crystal Structure of (PCl4)[Re2Cl9]
✍ A. I. Baranov; G. V. Khvorykh; S. I. Troyanov πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 German βš– 83 KB πŸ‘ 2 views

The reaction between PCl 3 and ReCl 5 yielded at 200 °C the ionic tetrachlorophosphonium dirhenium nonachloride, (PCl 4 )[Re 2 Cl 9 ]. Single crystal X-ray diffraction analysis revealed a monoclinic unit cell: a = 8.616(3) A Ê , b = 10.449(4) A Ê , c = 9.397(3) A Ê , b = 99.72(3)°, V = 833.9(5) A Ê

Synthesis, Crystal Structure, and Bondin
Synthesis, Crystal Structure, and Bonding of (PCl4)2[Mo2Cl10], the First Compound in Mo–P–Cl System
✍ G. V. Khvorykh; S. I. Troyanov; A. I. Baranov; A. A. Serov πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 German βš– 88 KB πŸ‘ 1 views

An ampule reaction between Mo and PCl 5 at 200 °C yielded (PCl 4 ) 2 [Mo 2 Cl 10 ], the first ternary compound in Mo±P±Cl system. Single crystal X-ray diffraction gave a triclinic unit cell: a = 6.870(1), b = 8.892(2), c = 9.423(2) A Ê , α = 100.24(2), b = 95.55(2), c = 96.12(2)°(V = 559.3(2) A Ê 3