## Abstract The theory of magnetic resonance Raman optical activity in metal porphyrins is developed. Irreducible tensor methods are used to calculate the transition polarizabilities (involving both symmetric and antisymmetric contributions) which are formulated in terms of a vibronic development o
Magnetic resonance-Raman optical activity of IrBr2−6
✍ Scribed by L.D. Barron; J. Vrbancich; R.S. Watts
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 283 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
M~gnc~c optic31 xtwity in resonance Raman spuctra of IrB$ are reported. Couplets are observed In alI three Ramsn fundamentals (Alg, Eg and Tzg) at 514.5 nm, but only m i%lg 31577.5 nm.Thcsc ongm~~c m ~nnnuons bcrwxn Zerman levels of the Knmersdcpeneratc ground SIUC. From the absolurc sifn in the AQ band, ~hc rsotroplcg iactor IS conrumcd
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