Observation of resonance electronic and non-resonance-enhanced vibrational natural Raman optical activity
β Scribed by Christian Merten; Honggang Li; Xuefang Lu; Andreas Hartwig; Laurence A. Nafie
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 184 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0377-0486
- DOI
- 10.1002/jrs.2750
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A vibrational resonance Raman effect of the totally symmetric Fe - F stretching mode at 453 cm^β1^is observed for high-spin tetra-n-butylammonium di(fluoro)tetraphenylporphyrinatoferrate(III). Typical A-term scattering with a high intensity overtone progression is proposed to be due to coincidence o
## Abstract A new tool for chiral vibrational spectroscopy is reported here. A surface enhanced effect was observed using Raman optical activity (ROA). This observation opens new possibilities for ROA as a tool for vibrational spectroscopy. The combination of surface enhanced effect (SE) and ROA in